The easiest way is if You have a lathe or a big drill press is to get a head holding fixture that screws in the spark plug hole and the spin the head and clean it with scotch bright and carb spray. You clean it and give it a good polishing at the same time. If You don’t have a way to spin it then use carb spray and scotch bright. And wear eye protection, Carb spray burns if it gets in Your eyes.
DO NOT spin a head in the drill press. There is a good chance it will come flying out. Those chucks are held in with a taper not good at taking side loads or vibrations of any kind.
You can scrape the carbon off with a small pen knife, just don’t dig in too hard or you’ll scratch the aluminum.